全文获取类型
收费全文 | 165篇 |
免费 | 2篇 |
专业分类
安全科学 | 1篇 |
废物处理 | 14篇 |
环保管理 | 17篇 |
综合类 | 22篇 |
基础理论 | 29篇 |
污染及防治 | 56篇 |
评价与监测 | 16篇 |
社会与环境 | 11篇 |
灾害及防治 | 1篇 |
出版年
2023年 | 5篇 |
2022年 | 10篇 |
2021年 | 15篇 |
2020年 | 5篇 |
2019年 | 2篇 |
2018年 | 8篇 |
2017年 | 9篇 |
2016年 | 17篇 |
2015年 | 5篇 |
2014年 | 10篇 |
2013年 | 15篇 |
2012年 | 5篇 |
2011年 | 11篇 |
2010年 | 7篇 |
2009年 | 5篇 |
2008年 | 6篇 |
2007年 | 7篇 |
2006年 | 4篇 |
2005年 | 5篇 |
2004年 | 3篇 |
2003年 | 1篇 |
2002年 | 1篇 |
2001年 | 1篇 |
2000年 | 1篇 |
1998年 | 1篇 |
1995年 | 3篇 |
1993年 | 2篇 |
1985年 | 1篇 |
1981年 | 1篇 |
1957年 | 1篇 |
排序方式: 共有167条查询结果,搜索用时 332 毫秒
61.
Maria J. Lima M. Enis Leblebici Madalena M. Dias José Carlos B. Lopes Cláudia G. Silva Adrián M. T. Silva Joaquim L. Faria 《Environmental science and pollution research international》2014,21(19):11116-11125
The degradation of ciprofloxacin was studied in aqueous solutions by using a continuous flow homogeneous photo-Fenton process under simulated solar light. The effect of different operating conditions on the degradation of ciprofloxacin was investigated by changing the hydrogen peroxide (0–2.50 mM) and iron(II) sulphate (0–10 mg Fe L?1) concentrations, as well as the pH (2.8–10), irradiance (0–750 W m?2) and residence time (0.13–3.4 min) of the process. As expected, the highest catalytic activity in steady state conditions was achieved at acidic pH (2.8), namely 85 % of ciprofloxacin conversion, when maintaining the other variables constant (i.e. 2.0 mg L?1 of iron(II), 2.50 mM of hydrogen peroxide, 1.8 min of residence time and 500 W m?2 of irradiance). Additionally, magnetite magnetic nanoparticles (ca. 20 nm of average particle size) were synthesized, characterized and tested as a possible catalyst for this reaction. In this case, the highest catalytic activity was achieved at natural pH, namely a 55 % average conversion of ciprofloxacin in 1.8 min of residence time and under 500 W m?2. Some of the photocatalytic activity was attributed to Fe2+ leaching from the magnetic nanoparticles to the solution. 相似文献
62.
Luciana S. Rocha I. Lopes Cláudia B. Lopes Bruno Henriques Amadeu M. V. M. Soares Armando C. Duarte Eduarda Pereira 《Environmental science and pollution research international》2014,21(13):8146-8156
In the present work, the efficiency of rice husk to remove Hg(II) from river waters spiked with realistic environmental concentrations of this metal (μg L?1 range) was evaluated. The residual levels of Hg(II) obtained after the remediation process were compared with the guideline values for effluents discharges and water for human consumption, and the ecotoxicological effects using organisms of different trophic levels were assessed. The rice husk sorbent proved to be useful in decreasing Hg(II) contamination in river waters, by reducing the levels of Hg(II) to values of ca. 8.0 and 34 μg L?1, for an Hg(II) initial concentration of 50 and 500 μg L?1, respectively. The remediation process with rice husk biowaste was extremely efficient in river waters spiked with lower levels of Hg(II), being able to eliminate the toxicity to the exposed organisms algae Pseudokirchneriella subcapitata and rotifer Brachionus calyciflorus and ensure the total survival of Daphnia magna species. For concentrations of Hg(II) tenfold higher (500 μg L?1), the remediation process was not adequate in the detoxification process, still, the rice husk material was able to reduce considerably the toxicity to the bacteria Vibrio fischeri, algae P. subcapitata and rotifer B. calyciflorus, whose responses where fully inhibited during its exposure to the non-remediated river water. The use of a battery of bioassays with organisms from different trophic levels and whose sensitivity revealed to be different and dependent on the levels of Hg(II) contamination proved to be much more accurate in predicting the ecotoxicological hazard assessment of the detoxification process by means of rice husk biowaste. 相似文献
63.
64.
To better understand the impacts posed by soil contamination to aquatic ecosystems it is crucial to characterise the links between ecotoxicity, chemical availability and geochemical reactivity of potentially toxic elements (PTE’s) in soils. We evaluated the adverse effects of water extracts obtained from soils contaminated by chemical industry and mining, using a test battery including organisms from different trophic levels (bacteria, algae and daphnids). These tests provided a quick assessment of the ecotoxicity of soils with respect to possible adverse effects on aquatic organisms although the ecotoxicological responses could be related to the solubility of PTE’s only to a limited extent.The analysis of results of bioassays together with the chemical characterisation of water extracts provided additional relevant insight into the role of conductivity, pH, Al, Fe, and Mn of soil extracts on toxicity to organisms. Furthermore, an important conclusion of this study was that the toxicity of extracts to the aquatic organisms could also be related to the soil properties (pH, Org C and Feox) and to the reactivity of PTE’s in soils which in fact control the soluble fraction of the contaminants.The combined assessment of ecotoxicity in water fractions, solubility and geochemical reactivity of PTE’s in soils provided a more comprehensive understanding of the bioavailability of inorganic contaminants than ecotoxicological or chemical studies alone and can therefore be most useful for environmental risks assessment of contaminated soils. 相似文献
65.
This article presents the results of the most recent estimation of polychlorinated dibenzo-p-dioxins (PCDD) and dibenzofurans (PCDF) atmospheric emissions in Portugal, which has covered the period 2004–2009 and includes 27 emission sources types. The results are compared with previous emissions inventories published for Portugal. The main objective of this work is to provide relevant information about the amounts of the compounds that are released into the atmosphere in Portugal, and identify their major sources and trends. 相似文献
66.
67.
Faria MS Lopes RJ Malcato J Nogueira AJ Soares AM 《Environmental pollution (Barking, Essex : 1987)》2008,151(1):213-221
In this study we evaluate the ability of an in situ bioassay with Chironomus riparius larvae, using larval development and growth as endpoints, to biomonitor water quality and to assess the biological recovery of metal contaminated freshwater ecosystems of mine areas that are subject of restoration measures. The bioassay was carried out in streams located near an abandoned goldmine in North Portugal, throughout an environmental rehabilitation of the mine (2002-2004). During this period, a decrease in the inhibition of larval growth in the metal contaminated stream was observed. The bioassay was also performed in streams located near an active tungsten mine in Central Portugal. Larval growth and development were highly inhibited in the stream that receives acid drainage from the tungsten mine and treated water from the AMD treatment station. The results indicate that the bioassay can be used to evaluate the efficiency of environmental restoration measures in mining areas. 相似文献
68.
Bigogno Rodrigo Gonçalves Dias Marcos Lopes Manhães Mariana Borges N. Sanchez Rodriguez Ruben J. 《Journal of Polymers and the Environment》2022,30(4):1228-1243
Journal of Polymers and the Environment - This study was developed a novel nanostructured membrane by electrospinning process, from polyacrylonitrile (PAN) modify by hydroxypropyl methylcellulose... 相似文献
69.
An assessment is made of the atmospheric emissions from the life cycle of fuel ethanol coupled with the cogeneration of electricity from sugarcane in Brazil. The total exergy loss from the most quantitative relevant atmospheric emission substances produced by the life cycle of fuel ethanol is 3.26E+05 kJ/t of C2H5OH. Compared with the chemical exergy of 1 t of ethanol (calculated as 34.56E+06 kJ), the exergy loss from the life cycle's atmospheric emission represents 1.11% of the product's exergy. The activity that most contributes to atmospheric emission chemical exergy losses is the harvesting of sugarcane through the methane emitted in burning. Suggestions for improved environmental quality and greater efficiency of the life cycle of fuel ethanol with cogenerated energy are: harvesting the sugarcane without burning, renewable fuels should be used in tractors, trucks and buses instead of fossil fuel and the transportation of products and input should be logistically optimized. 相似文献
70.
Kosman Joslaine Monteiro João Frederico Haas Leandro Lenart Vinícius Mariani Weinert Patrícia Los Tiburtius Elaine Regina Lopes 《Environmental science and pollution research international》2021,28(19):24046-24056
Environmental Science and Pollution Research - This study presents the results obtained for the optimization of the mineralization of losartan (LOS) and hydrochlorothiazide (HCTZ) using the... 相似文献